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Completing the Triad: Synthesis and Full Characterization of Homoleptic and Heteroleptic Carbonyl and Nitrosyl Complexes of the Group VI Metals

Jan BohnenbergerManuel SchmittWolfram FeuersteinIvo KrummenacherBurkhard ButschkeJakub CzajkaPrzemyslaw J. MalinowskiFrank BreherIngo Krossing

出版	Universität, 2020
URL	http://books.google.com.hk/books?id=1FCrzQEACAAJ&hl=&source=gbs_api

註釋

Abstract: Oxidation of M(CO)6 (M = Cr, Mo, W) with the synergistic oxidative system Ag[WCA]/0.5 I2 yields the fully characterized metalloradical salts [M(CO)6]+ ̇[WCA]− (weakly coordinating anion WCA = [F-{Al(ORF)3}2]−, RF = C(CF3)3). The new metalloradical cations with M = Mo and W showcase a similar structural fluxionality as the previously reported [Cr(CO)6]+ ̇. Their reactivity increases from M = Cr