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Morphology and Dynamics of Bottlebrush Polymers
Karin J. Bichler
出版
Springer Nature
, 2021-09-24
主題
Technology & Engineering / Materials Science / General
Science / Chemistry / Physical & Theoretical
Science / Physics / Crystallography
Science / Mechanics / Fluids
Technology & Engineering / Manufacturing
Science / Physics / Condensed Matter
Science / Physics / General
ISBN
3030833798
9783030833794
URL
http://books.google.com.hk/books?id=3cFEEAAAQBAJ&hl=&source=gbs_api
EBook
SAMPLE
註釋
This thesis makes significant advances to the understanding of bottlebrush polymers. While bottlebrushes have received much attention due to the recent discovery of their unprecedented properties, including supersoftness, ultra-low viscosity, and hyperelasticity, this thesis is the first fundamental investigation at the molecular level that comprises structure and dynamics. Neutron scattering experiments, detailed within, reveal spherical or cylindrical shapes, instead of a random coil conformation. Another highlight is the analysis of the fast dynamics at the sub nm-length scale. The combination of three neutron spectrometers and the development of a new analysis technique enabled the calculation of the mean-square displacement over seven orders of magnitude in time scale. This unprecedented result can be applied to a broad class of samples, including polymers and other materials. The thesis is accessible to scientists from other fields, provides the reader with easily understandable guidelines for applying this analysis to other materials, and has the potential to make a significant impact on the analysis of neutron scattering data.