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Investigations of HRC®-Stimulated Bioreduction of Cr(VI) at Hanford 100H.
J. Peterson
K. Williams
T. Tokunaga
P. E. Long
T. C. Hazen
B. Faybishenko
K. Cantrell
C. T. Resch
J. Wan
D. Newcomer
M. Firestone
S. Borglin
S. Hubbard
S. Koenigsberg
E. Brodie
D. Joyner
A. Willet
出版
United States. Department of Energy. Office of Science
, 2006
URL
http://books.google.com.hk/books?id=6f3DjwEACAAJ&hl=&source=gbs_api
註釋
Hypothesis: Lactate (Hydrogen Release Compound-HRC{trademark}) injection into chromium contaminated groundwater through an injection well will cause indirect or direct bioreduction of chromate [Cr(VI)] and precipitation of insoluble species of [Cr(III)] on soil particles, probably catalyzed at oxide surfaces, at the field scale. Objective: Assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford Site's 100-H Area field site. Types of Research: A three-well system (injection well and upgradient and downgradient monitoring wells) was used for conducting the in situ biostimulation and monitoring. To assess the pre- and post-injection test groundwater conditions, we used an integrated monitoring approach, involving hydraulic, geochemical, microbial, and geophysical techniques and analytical methods, as well as conducted five Br-tracer injection tests and four pumping tests (concurrently with the Br-tracer tests). Groundwater biostimulation was conducted by injection of 40 lbs of {sup 13}C-labeled HRC into the injection well (over the depth interval from 44-50 ft) on 8/3/2004, followed by low-flow pumping (1.2 to 2.5 l/min) through the downgradient well (to ensure capture of groundwater flow lines passing through the injection well) for 27 days. Main Results: Although the total microbial population in sediments is relatively low (