返回Google圖書搜尋

Observation and Identification of Ion Dissociation Processes Occurring in the Drift Tube of a Time-of-flight Mass Spectrometer

W. W. Hunt (Jr.)Robert E. HuffmanK. E. McGee

出版	Air Force Cambridge Research Laboratories, Office of Aerospace Research, United States Air Force, 1963
URL	http://books.google.com.hk/books?id=CRgXjEbTd64C&hl=&source=gbs_api
EBook	FULL_PUBLIC_DOMAIN

註釋The shifts in ion flight times produced by a flat-top potential barrier applied within the drift tube of a time-of-flight mass spectrometer are defined analytically in terms of the height of the potential barrier. These flight-time shifts are selectively dependent on the mass, charge, and kinetic energy of the ions involved; consequently, they can be used to spearate and identify the products of ion dissociation processes occurring in the drift tube. Comparisons of calculated and observed flight-time shifts for the 58 + to 43+, 42+ dissociations in n-butane are used to illustrate the applicability and present limitations of this method of identifying dissociation products. (Author).