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Thermal Electrocyclic Reactions
Elliot Marvell
出版Elsevier, 2012-12-02
主題Science / Chemistry / OrganicScience / Chemistry / General
ISBN03231504549780323150453
URLhttp://books.google.com.hk/books?id=CjGEI1isL0kC&hl=&source=gbs_api
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註釋Thermal Electrocyclic Reactions explores the applications of thermal electrocyclic reactions to stereospecific synthesis. This book is divided into nine chapters, and begins with a presentation of the theory of electrocylic reactions using orbital conversions through symmetry operations and correlation diagrams. Considerable chapters are devoted to various conjugate systems entering an electrocyclic process, including two-electron, four electron-three-, four-, and five-atom, and six electron-five-, and six-atom systems. The remaining chapters examine the electrocyclic reaction of longer systems, including eight or more p electrons, as well as conjugated systems with an odd number of electrons, which constitute a special case in the conservation of orbital symmetry. This book will be of great value to organic chemists and researchers.