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The Development of Organic Peroxide Mediated Oxidations

Stuart Cameron Davidson

出版	2018
URL	http://books.google.com.hk/books?id=PCuO0AEACAAJ&hl=&source=gbs_api

註釋

Chapter 1 describes a novel metal-free method for the one-pot anti-dihydroxylation of alkenes to form diols using malonoyl peroxide 13. The reaction conditions were optimised and the scope of the optimal conditions were examined with a variety of stilbene, styrene and indene derivatives to give the corresponding anti-diols in good to excellent yields and selectivities. Following this, a variety of mechanistic investigations were undertaken, revealing key intermediates and allowing the proposal of a mechanism. Scheme 1-1. Optimised conditions of anti-dihydroxylation discussed in Chapter 1. [see thesis for graphic representation].