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Structure, magnetism and low thermal expansion in Tb1-xErxCo2Mny intermetallic compounds

Yanming SunYili CaoYang RenSaul H. LapidusQiang LiJinxia DengJun MiaoKun LinXianran Xing

出版	OAE Publishing Inc., 2023-06-16
主題	Technology & Engineering / Materials Science / General
URL	http://books.google.com.hk/books?id=U5X3EAAAQBAJ&hl=&source=gbs_api
EBook	SAMPLE

註釋

Here, we obtained a series of controllable thermal expansion alloys Tb1-xErxCo2Mny (x = 0-0.5, y = 0-0.4) by incorporating double rare earth doping and introducing non-stoichiometric Mn content. By varying the amount of Er or Mn, a low thermal expansion (LTE) is achieved in Tb0.6Er0.4Co2Mn0.1 (TECM, α1 = 1.23 × 10-6 K-1, 125~236 K). The macroscopic linear expansion and magnetic properties reveal that anomalous thermal expansion is closely related to the magnetic phase transition. Synchrotron X-ray powder diffraction results show that TECM is a cubic phase (space group: Fd-3m) at high temperatures, and a structural transition to a rhombohedral phase (space group: R-3m) occurs as temperature decreases. The negative thermal expansion c-axis compensates for the normal positive thermal expansion of the basal plane, resulting in the volumetric LTE. This study provides a new metallic and magnetic ZTE material.