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The Development and Application of Thiosquaramides and Bispyridiniums as Hydrogen-bond Donor Catalysts
Michael Gregorio Rombola
出版ProQuest Dissertations & Theses, 2018
ISBN04380885499780438088542
URLhttp://books.google.com.hk/books?id=almWwgEACAAJ&hl=&source=gbs_api
註釋Chiral hydrogen-bond donor molecules have emerged as powerful catalysts for asymmetric organic synthesis. Principles of hydrogen-bond donor catalyst design have led to the development of thiosquaramides and bispyridiniums as highly active catalysts. The synthesis and catalytic performance of thiosquaramide and bispyridinium catalophores is described, as well as their application to new methodologies, in particular highly enantioselective Michael additions of barbituric acids to nitroalkenes and nitro-Diels-Alder reactions.