The Total Syntheses of Picrotoxinin, Picrotin, Corianin and Methyl Picrotoxate ; a Chemoselective Approach to the Indolocarbazole Family of Natural Products Via the Palladium Catalyzed Asymmetric Allylation Reaction ; Palladium Mediated Catalytic Asymmetric Allylative Cyclizations of Amine Nucleophiles