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DISSOLUTION OF ACIDIC AND BASIC COMPOUNDS FROM THE ROTATING DISK: INFLUENCE OF DIFFUSION, CONVECTION, AND REACTION.

DANIEL PATRICK MCNAMARA

出版	University of MICHIGAN, 1986
URL	http://books.google.com.hk/books?id=ikBtAAAAMAAJ&hl=&source=gbs_api

註釋

ionization-produced species, and the ability to make a priori predictions without fitting film thicknesses or diffusion coefficients. In the buffered case, all the complex buffer equilibria could be simplified to a single flux boundary condition. The model accurately predicted the dissolution rate using independently obtained values for the solubility, pK(,a), and diffusion coefficient of the compound. For dissolution in buffers, the ionization constants of the buffer were also needed. The model could