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Radiation-Induced Changes in Reactivity of Ammonium Perchlorate
D. A. Anderson
E. S. Freeman
出版
ASTM International
, 1964
URL
http://books.google.com.hk/books?id=jMR6zgEACAAJ&hl=&source=gbs_api
註釋
Exposure to X-ray and gamma-ray radiation profoundly alters the thermal stability and decomposition characteristics of ammonium perchlorate in the solid state. The radiation-induced changes in chemical reactivity were revealed by investigations involving thermogravimetric experiments and differential thermal analysis, where temperature is increased continuously at a constant rate, isothermal rate studies as a function of temperature, hot stage microscopic and X-ray diffraction studies, and electron spin resonance. This paper presents both a review and evaluation of recent investigations and new experimental results and interpretations of the reaction mechanisms.