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Some Thermodynamic Values for Four Titanium Halides

Edward G. KingW. W. WellerA. U. ChristensenKenneth Keith Kelley

出版	U.S. Department of the Interior, Bureau of Mines, 1961
URL	http://books.google.com.hk/books?id=6cW22B6h5SwC&hl=&source=gbs_api

註釋

Many of the existing thermodynamic values for the titanium halides are estimates, including all the entropies and high-temperature heat contents of their crystalline and liquid phases. This report contains the results of low-temperature heat-capacity measurements (which lead to entropy values at 298.15° K.) and high-temperature heat-content measurements of four halides - trichloride, tribromide, tetrabromide, and tetraiodide. The new data are combined with selected heat-of-formation values at 298.15° K. to obtain improved values of the heats and free energies of formation of these halides at high temperatures, thus supplementing the previous data of Kelly and Mah.